Double activation of the diphosphinite pincer proligand by a triosmium carbonyl cluster

Autor:	Dmitry A. Panov, Avthandil A. Koridze, Vasily V. Krivykh, Fedor M. Dolgushin
Rok vydání:	2020
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Thermal decomposition General Chemistry 010402 general chemistry 01 natural sciences Toluene Medicinal chemistry 0104 chemical sciences Pincer movement
Zdroj:	Mendeleev Communications. 30:374-376
ISSN:	0959-9436
Popis:	The reaction between 1,3-bis(diphenylphosphinite)-benzene and Os3(CO)10(MeCN)2 affords complex Os3(CO)10[1,3-(PhPO)2C6H4]. A thermolysis of this cluster in refluxing toluene results in the activation of O–PPh2 and C–H bonds and the formation of unsaturated triosmium cluster Os3(μ-H)(μ-PPh2)(CO)7[(C6H3(O)(OPPh2)] that possesses a remarkable structure with the pseudo-pincer ligand containing a bridging μ-η1-aryl group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b744a0004dcbf2da65f215128955f97e https://doi.org/10.1016/j.mencom.2020.05.038 Zobrazit plný text záznamu Full Text from ScienceDirect