Liquid phase hydrogenolysis of dibenzyl ether over metals of the VIIIth group

Autor:	E. F. Litvin, V. Z. Sharf, S. V. Rusina
Rok vydání:	1993
Předmět:	Solvent Benzaldehyde chemistry.chemical_compound chemistry Benzyl alcohol Hydrogenolysis Decarbonylation Organic chemistry Ether General Chemistry Toluene Medicinal chemistry Catalysis
Zdroj:	Russian Chemical Bulletin. 42:1200-1203
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf00702006
Popis:	It has been shown that depending on the catalyst and the solvent used, during the conversion of dibenzyl ether to toluene hydrogenolysis of C-O ether bonds, dehydrogenation and hydrogenolysis of benzyl alcohol formed, hydrogenation and decarbonylation of benzaldehyde, and the recombination of benzyl radicals and the benzylation of toluene can take place. The activity of catalysts in hydrogenolysis reactions of dibenzyl ether and benzyl alcohol to produce toluene decreases as follows: Pd/C>Pd>Raney Ni>Rh, whereas the selectivity drops down in the order: Raney Ni>Pd>Pd/C>Rh. The reaction rates depend on the solvent and diminish in the order: ethanol>2-propanol>benzene.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b71ba60718d03867031f0f552f9cce3e https://doi.org/10.1007/bf00702006 Zobrazit plný text záznamu Full text from SpringerLink