Generation of vinyl cations by nitrosation ofN-silylated imines and enamines

Autor:	Lakshminarayanapuram R. Subramanian, Michael Hanack, Roberto martínez Alvarez
Rok vydání:	1993
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Nitrosation Organic chemistry Reaction intermediate Physical and Theoretical Chemistry Carbocation Aliphatic compound Enamine Dichloromethane
Zdroj:	Journal of Physical Organic Chemistry. 6:44-46
ISSN:	0894-3230
DOI:	10.1002/poc.610060107
Popis:	The reaction of monosilylated imines and a disilylated enamine with nitrosyl salts in dichloromethane at − 78 °C is shown to proceed via intermediate vinyl diazonium salts and vinyl cations
Databáze:	OpenAIRE
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