Superhyperfine structure of the ESR spectrum of the Cu+2 ion in the ZnWO4 lattice

Autor:	V. G. Pitsyuga, M. V. Mokhosoev, V. I. Petrenko
Rok vydání:	1974
Předmět:	Materials science Magnetic moment Condensed matter physics Isotope Lattice (order) Nuclear magnetic moment Analytical chemistry General Physics and Astronomy Electron Spectral component Ion
Zdroj:	Soviet Physics Journal. 17:1236-1239
ISSN:	1573-9228 0038-5697
Popis:	When present in the ZnWO4 lattice in quantities of less than 0.005%, the Cu+2 ion exhibits an ESR spectrum with a superhyperfine structure of the ligand type at liquid-helium temperature. This is due to the interaction of the 3d9 electrons of the Cu+2 ion with the nuclear magnetic moments of the W183 isotopes (14.4%) lying along the z axis; the superhyperfine interaction constant is equal to 7.4±0.4 G. On increasing the concentration of the Cu+2 ions the superhyperfine structure of the spectrum no longer appears. Calculations of the intensities of the spectral components agree satisfactorily with experimental data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b6f29d5394eec2ff89123754b230c488 https://doi.org/10.1007/bf01208672 Zobrazit plný text záznamu Full text from SpringerLink