Theoretical studies on the mechanism of molybdenum-catalysed deoxydehydration of diols
| Autor: | Federico Verdicchio, Agustín Galindo |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Dalton Transactions. 52:5935-5942 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d3dt00340j |
| Popis: | The deoxydehydration of vicinal diols, using a phosphane as a reductant and catalysed by Mo-complexes, follows a mechanism in which an oxygen atom transfer of the Mo complex to the phosphane occurs before diol activation, according to DFT studies. |
| Databáze: | OpenAIRE |
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