On the Alkaline Degradation of 2-Furfurylidene-10-methyl-trans-1-decalone

Autor:	A. Stoessl, J.B. Stothers
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Aqueous solution Base (chemistry) chemistry Organic Chemistry Degradation (geology) Organic chemistry General Chemistry Catalysis
Zdroj:	Canadian Journal of Chemistry. 53:3359-3364
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v75-479
Popis:	The reaction of 2-furfurylidene-10-methyl-trans-1-decalone with base (NaOH – aqueous HOCH2CH2OH) has been reinvestigated and found to give nine products. Elucidation of the structures of eight of these products, which accounted for ca. 80% of the process, was accomplished from their spectroscopic data and confirmed by chemical interconversions. The product mixture obtained shows that the reaction involves competition between the retroaldol process and various hydride reductions with some allylic isomerization.
Databáze:	OpenAIRE
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