Kinetics of the manganese(III)–vanadium(IV) electron-transfer reaction in aqueous perchlorate solution

Autor:	M. J. Nicol, D. R. Rosseinsky
Rok vydání:	1968
Předmět:	Aqueous solution Inorganic chemistry Kinetics Cationic polymerization Vanadium chemistry.chemical_element Manganese Inorganic Chemistry Perchlorate chemistry.chemical_compound Electron transfer Reaction rate constant chemistry Physical and Theoretical Chemistry
Zdroj:	J. Chem. Soc. A. :1022-1024
ISSN:	0022-4944
DOI:	10.1039/j19680001022
Popis:	The rate law d[VV]/dt=kobs[VIV][MnIII] holds for the range 5–20° and 0·8–3·0M-HClO4, kobs being 9·2 × 103 l. mole–1 min.–1 at 20° and 3M. The kinetic data provide further evidence of the appreciable hydrolysis of manganese(III), in the [HClO4]-dependence of kobs. Rate constants for reactions of vanadium(IV) with several cationic oxidants are shown to follow just the same sequence as those for the corresponding reactions of iron(II).
Databáze:	OpenAIRE
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