Stereoselective electrochemical synthesis of silyl enol ethers using a sacrificial magnesium anode

Autor:	Jacques Dunogues, Claude Biran, Michel Bordeau, Dominique Bonafoux
Rok vydání:	1995
Předmět:	Silylation Chemistry Magnesium Organic Chemistry Inorganic chemistry chemistry.chemical_element Electrochemistry Biochemistry Enol Anode Inorganic Chemistry chemistry.chemical_compound Deprotonation Materials Chemistry Stereoselectivity Chelation Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 493:27-32
ISSN:	0022-328X
DOI:	10.1016/0022-328x(94)05368-l
Popis:	The 2-pyrrolidone magnesium salt electrogenerated in an undivided cell fitted with a sacrificial magnesium anode allowed the stereoselective synthesis of Z-silyl enol ethers upon deprotonation of enolizable ketones in the presence of a complexing agent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b6d83f996a9532cf6537d40eadbc7280 https://doi.org/10.1016/0022-328x(94)05368-l Zobrazit plný text záznamu Full Text from ScienceDirect