O–CN Bond Cleavage of Cyanates by a Transition-Metal Complex

Autor:	Kozo Fukumoto, Nobuaki Koga, Kazumasa Hayasaka, Tsukuru Oya, AbdelRahman A. Dahy, Hiroshi Nakazawa, Masumi Itazaki
Rok vydání:	2012
Předmět:	Inorganic Chemistry Alpha cleavage Silylation Transition metal Chemistry Organic Chemistry Polymer chemistry chemistry.chemical_element Physical and Theoretical Chemistry Photochemistry Nitrogen Bond cleavage Catalysis
Zdroj:	Organometallics. 31:787-790
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om201257h
Popis:	O–CN bond cleavage of cyanates (ROCN) has been achieved at room temperature in the reaction of ROCN with a methyl Fe, Mo, or W complex. A mechanistic investigation involving DFT calculations revealed that silyl migration from Mo to the CN nitrogen gave an N-silylated η2-imidato Mo complex. This intermediate analogue was isolated and characterized by X-ray analysis. Catalytic O–CN bond cleavage was achieved using Cp(CO)3MoMe under thermal conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b6d5ef89d7ba8b98f17c3209276d052f https://doi.org/10.1021/om201257h Zobrazit plný text záznamu