Characterization of Neutral Versus Anionic Superabsorbent Polymers (SAPs) in Ion-Rich Solutions for Their Use as Internal Curing Agents

Autor: Parawee Tangkokiat, Jirawan Siramanont, Wanwipa Siriwatwechakul, Thanapat Thanapornpavornkul, Surapit Muangkaew, Chalermwut Snguanyat
Rok vydání: 2019
Předmět:
Zdroj: 3rd International Conference on the Application of Superabsorbent Polymers (SAP) and Other New Admixtures Towards Smart Concrete ISBN: 9783030333416
Popis: Predominant SAPs used for internal curing are anionic gels, such as polyacrylamide, polyacrylic acid, and polyacrylate. They contain or can be hydrolyzed to form carboxylate functional groups. This allows them to retain water up to a few hundred times their dry weight, especially in a high pH environment. SAPs’ swelling behavior is desirable, but other characteristics of SAPs are important for their application as internal curing agents. These anionic SAPs are not only sensitive to the pH environment but also the types of ions. SAPs show less swelling in a calcium-rich solution than in a sodium-rich solution at the same pH. This has direct implications for internal curing because the cement pore solution is rich in various kinds of cations.
Databáze: OpenAIRE