Synthesis and Characterization of Radical Cation Salts Derived from Tetraselenafulvalene and Bis(Ethy1enedithio)tetraselenafulvalene

Autor:	C. Husting, L. Itlley, John C. Huffman, Jack M. Williams, J.D. Dudek, K. D. Carlson, G.A. Yaconi, T. Burgin, Lawrence K. Montgomery, Urs Geiser
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Radical ion chemistry Bicyclic molecule Phase (matter) Polymer chemistry Salt (chemistry) Organic chemistry Condensed Matter Physics
Zdroj:	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 211:283-288
ISSN:	1058-725X
Popis:	New synthetic routes to bis(ethylenedithio)tetraselenafulvalene (BETS) were explored, starting from tetraselenafulvalene (TSF). Several radical cation salts of TSF and BETS were prepared by electrocrystallization. A new kappa phase salt of BETS, K-(BETS)2GaCl4, displayed an interesting resistance-temperature profile from 300-35K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b6aa3fa66bb1885227b1acd269e2f830 https://doi.org/10.1080/10587259208025827 Zobrazit plný text záznamu