Characteristics of the complexing of chitosan with sodium dodecyl sulfate, according to IR spectroscopy data and quantum-chemical calculations
| Autor: | V. P. Barabanov, K. A. Romanova, A. Ya. Tret’yakova, Yu. G. Galyametdinov, S. V. Shilova |
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| Rok vydání: | 2016 |
| Předmět: |
Quantum chemical
Inorganic chemistry technology industry and agriculture Infrared spectroscopy Protonation 02 engineering and technology equipment and supplies 010402 general chemistry 021001 nanoscience & nanotechnology Quantitative Biology::Genomics 01 natural sciences Polyelectrolyte 0104 chemical sciences Ion Solvent Chitosan chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Sodium dodecyl sulfate 0210 nano-technology |
| Zdroj: | Russian Journal of Physical Chemistry A. 90:1181-1184 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s003602441606025x |
| Popis: | The complexing of protonated chitosan with dodecyl sulfate ions in water solutions is studied using IR spectroscopy data and quantum-chemical calculations. It is established that the electrostatic interaction between the protonated amino groups of chitosan and dodecyl sulfate ions is apparent in the IR spectrum as a band at 833 cm−1. The need to consider the effect the solvent has on the formation of hydrogen-bound ion pairs [CTS+ ⋅ C12H25O3-] is shown via a quantum-chemical simulation of the equilibrium geometry and the energy characteristics of complexing and hydration. |
| Databáze: | OpenAIRE |
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