Ru catalyzed hydrogenation of CO2 to formate under basic and acidic conditions

Autor:	Caroline T. Saouma, Austin T. Cannon
Rok vydání:	2021
Předmět:	Inorganic Chemistry Tris chemistry.chemical_compound chemistry Ligand Materials Chemistry Formate Physical and Theoretical Chemistry Combinatorial chemistry Phosphine Catalysis
Zdroj:	Polyhedron. 207:115375
ISSN:	0277-5387
Popis:	The hydrogenation of CO2 to MeOH is pertinent to advance future energy schemes. Towards this end, phosophine-ligated Ru catalysts have been shown to achieve this transformation under either acidic or basic conditions. In this manuscript, we screen catalytic conditions for a novel tris(phosphine) ligand with Ru to see if it can facilitate the conversion of CO2 to MeOH under both acidic and basic conditions. With both sets of conditions, we observe hydrogenation of CO2 to formate. This work shows that the same catalytic system can function under both reaction types but is limited to formate production.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b6a5876539e0a935ce64886e0e1bbdaa https://doi.org/10.1016/j.poly.2021.115375 Zobrazit plný text záznamu Full Text from ScienceDirect