Syntheses, Crystal Structures, and Weak Interactions of Two 4-Substituted Benzyl Triphenylphosphonium Salts Containing Tetrachloromanganate(II) Anion
| Autor: | Ye-Long Qian, Xiao-Xu Zheng, Hua-Tang Cai, Xue-Ni Lin, Xiao-Ping Liu, Le-Min Yang, Jia-Rong Zhou, Man-Na Li, Yan-Hui Pan, Hui-Qing Ye |
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| Rok vydání: | 2015 |
| Předmět: |
Chemistry
Hydrogen bond Stereochemistry Stacking Molar conductivity Crystal structure Triclinic crystal system 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences Ion Inorganic Chemistry Crystallography Physical and Theoretical Chemistry Coordination geometry Monoclinic crystal system |
| Zdroj: | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 46:495-501 |
| ISSN: | 1553-3182 1553-3174 |
| DOI: | 10.1080/15533174.2014.988798 |
| Popis: | Two new tetrachloromanganate(II) salts, [4FBzTPP]2[MnCl4] (1) and [4ClBzTPP]2[MnCl4]·2H2O (2) ([4FBzTPP]+ = 1-(4′-fluorobenzyl)triphenylphosphonium; [4ClBzTPP]+ = 1-(4′-chlorobenzyl)triphenylphosphonium), have been prepared and characterized by elemental analyses, UV-Vis, IR, ESI-MS, molar conductivity and single-crystal X-ray diffraction. The single-crystal structure analysis shows that compound 1 crystallizes in the monoclinic space group P21/c, while 2 is triclinic P-1. Both 1 and 2 comprise one [MnCl4]2– anion and two cations, and the [MnCl4]2– anion exhibits distorted tetrahedral coordination geometry. The C‒H···Cl, C‒H···π hydrogen bonds and π···π stacking interactions in 1 and the C‒H···Cl, O‒H···Cl hydrogen bonds in 2 result in the forming of a 3D network structure in the solids. |
| Databáze: | OpenAIRE |
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