Photo-induced ring-closure via a looped flow reactor
| Autor: | Tanja Junkers, Evelien Baeten, Christopher Barner-Kowollik, Maarten Rubens, Kilian N. R. Wuest |
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| Rok vydání: | 2017 |
| Předmět: |
Fluid Flow and Transfer Processes
chemistry.chemical_classification Materials science 010405 organic chemistry Process Chemistry and Technology Flow (psychology) Polymer 010402 general chemistry Ring (chemistry) 01 natural sciences Catalysis 0104 chemical sciences Closure (computer programming) Chemical engineering chemistry Chemistry (miscellaneous) Chemical Engineering (miscellaneous) Volume concentration Macromolecule |
| Zdroj: | Reaction Chemistry & Engineering. 2:826-829 |
| ISSN: | 2058-9883 |
| DOI: | 10.1039/c7re00124j |
| Popis: | Looped flow processes are an efficient and versatile tool to synthesize complex macromolecular materials. Especially for light-induced ring-closure reactions, which typically require low concentrations, looped flow processes are critical for upscaling. Here, such a reactor was designed to carry out a photo-induced ring-closure reaction via a photo-enol reaction for the synthesis of cyclic polymers, leading to a reduction of required solvent in the synthesis by over a factor of 40, hence giving access to a more economical and fully scalable process. |
| Databáze: | OpenAIRE |
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