Antiradical activity of dioxolane derivatives

Autor:	T.V. Pokholok, A. V. Malkova, N. L. Komissarova, V. B. Vol'eva, E. Ya. Davydov, I. S. Belostotskaya
Rok vydání:	2013
Předmět:	Chemistry Radical Organic Chemistry Photodissociation Benzoyl peroxide Medicinal chemistry Chloride Redox chemistry.chemical_compound Radical ion Dioxolane medicine Organic chemistry Vicinal medicine.drug
Zdroj:	Russian Journal of Organic Chemistry. 49:446-449
ISSN:	1608-3393 1070-4280
DOI:	10.1134/s1070428013030226
Popis:	1,3-Benzodioxoles synthesized by condensation of 3,6-di-tert-butylbenzene-1,2-diol with carbonyl compounds showed antiradical activity due to their ability to undergo one-electron oxidation with formation of stable radical cations. On this basis, the antiknock effect of their structural analogs, 1,3-dioxolanes derived from vicinal diols, was interpreted in terms of oxidation of these compounds with active radicals generated from fuel hydrocarbons to produce more stable radical or radical ion species, depending on the fuel composition. The formation of radical species was detected in model oxidation reactions of 2,2-dimethyl-1,3-dioxolane and 2,2-dimethyl-1,3-dioxolan-4-ylmethanol with radicals generated by photolysis of iron(III) chloride and benzoyl peroxide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b668007570101f89350ccfee3de0e145 https://doi.org/10.1134/s1070428013030226 Zobrazit plný text záznamu Plný text ve formátu PDF