A Monocationic Zn(II) Acetate Complex of a Chiral Bisamidine Dioxolane Ligand, Naph-diPIM-dioxo-R, for the Asymmetric 1,3-Dipolar Cycloaddition of Tridentate α-Substituted α-Imino Esters and Acrylates to Multi-Substituted Prolines: Importance of an n-π* Interaction for High Enantioselectivity

Autor:	Shinji Tanaka, Indukuru Naga Chaithanya Kiran, Kazuki Fujita, Kazuki Kobayashi, Masato Kitamura
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Chemistry Ligand Dioxolane 1 3-Dipolar cycloaddition chemistry.chemical_element General Chemistry Bisamidine Medicinal chemistry Oxygen Reaction site
Zdroj:	Bulletin of the Chemical Society of Japan. 94:295-308
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.20200266
Popis:	A monocationic Zn(II) acetate complex of a C2-chiral bisamidine-type sp2N bidentate ligand (LR) possessing two dioxolane oxygen n orbitals in the reaction site catalyzes, without the use of an exte...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b663139a8567d42cdeb4b55db3f62800 https://doi.org/10.1246/bcsj.20200266 Zobrazit plný text záznamu