Adsorption of gases by microporous adsorbents. Communication 3. Nitrogen/krypton/xenon-microporous adsorbent carbon systems

Autor: N. S. Polyakov, M. M. Dubinin, K. M. Nikolaev
Rok vydání: 1985
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:238-242
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00951260
Popis: 1. Earlier studies of the adsorption of nitrogen, krypton, and xenon by microporous adsorbent carbons have been thoroughly analyzed. 2. The method for calculating adsorption isotherms at supercritical temperatures proposed by Dubinin and Kadlets on the basis of the theory of volumetric filling of micropores and the widely known experimental linearity of adsorption isosteres is in satisfactory agreement with experimental data, in particular at high pressure as shown by nitrogen. 3. The coefficient of thermal expansion of adsorbate depends on the size of adsorbent carbon micropores.
Databáze: OpenAIRE