Hydrate Isomerism in Coordination Polymers of Bismuth and Acetylenedicarboxylate

Autor:	Irena Stein, Stefanie Busch, Uwe Ruschewitz
Rok vydání:	2012
Předmět:	Aqueous solution Acetylenedicarboxylic acid Acetylenedicarboxylate Inorganic chemistry chemistry.chemical_element Crystal structure Isothermal process Bismuth Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Hydrate Single crystal
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 638:2098-2101
ISSN:	0044-2313
DOI:	10.1002/zaac.201200006
Popis:	Single crystals of [Bi(ADC)2/4(ADC)3/3(H2O)2]·2H2O (P, Z = 2) and [Bi(ADC)2/4(ADC)3/3(H2O)3]·H2O (P, Z = 2) were obtained by isothermal evaporation of aqueous solutions containing acetylenedicarboxylic acid (H2ADC) and Bi(NO3)3·5H2O. Their crystal structures were solved and refined from X-ray single crystal data. They are hydrate isomers with respect to the central Bi3+ ion, which leads to completely different topologies of the resulting coordination polymers.
Databáze:	OpenAIRE
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