Comprehensive effort on electrode slurry preparation for better electrochemical performance of LiFePO4 battery
| Autor: | Vinay A. Juvekar, Raghavan Gopalan, Sahana B. Moodakare, P. Logesh Kumar, Kumari Konda, Jyoti R. Seth, Manjusha Battabyal |
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| Rok vydání: | 2020 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology Exchange current density 02 engineering and technology Carbon black Current collector engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology Microstructure 01 natural sciences Lithium-ion battery 0104 chemical sciences Coating Electrode Slurry engineering Electrical and Electronic Engineering Physical and Theoretical Chemistry Composite material 0210 nano-technology |
| Zdroj: | Journal of Power Sources. 480:228837 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2020.228837 |
| Popis: | For a given proportion of active material, conductive agent, and binder, performance of the lithium ion battery depends on microstructure of the electrode. Uniform distribution of de-agglomerated particles of carbon black on the active material in the slurry is crucial for establishing a conductive network around the active particles and for improving the adhesion of the electrode to the current collector. Herein, we demonstrate that pre-mixing of carbon black and LiFePO4 via dry ball-milling achieves the desired microstructure in the electrode coating. Homogeneity of slurry of LiFePO4 in Poly(vinylidene fluoride)/N-methyl -2-pyrrolidone is demonstrated using measurement of viscosity and dynamic light scattering. Dried electrodes are shown to be uniform via SEM imaging and by a novel “linearly resolved electrical resistivity measurement” technique. Through peel tests it is shown that adhesion of the electrode to the current collector is improved. These improvements reflect in the electrochemical characteristics of the electrode such as increased cycling stability, higher exchange current density and ability of the electrode to perform at a higher C-rate. The electrodes prepared with this method, at an optimal composition, give a higher discharge voltage of ~3 V at 10 C compared to values of 2.4–2.8 V reported for unmodified LiFePO4 so far. |
| Databáze: | OpenAIRE |
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