| Autor: |
John E. Bercaw, Thomas C. McKenzie, Robert D. Sanner |
| Rok vydání: |
1975 |
| Předmět: |
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| Zdroj: |
Journal of Organometallic Chemistry. 102:457-466 |
| ISSN: |
0022-328X |
| DOI: |
10.1016/s0022-328x(00)89390-0 |
| Popis: |
The structure of bis(pentamethylcyclopentadienyl)dichlorotitanium(IV) has been investigated by single-crystal X-ray diffraction techniques. [η-C 5 (CH 3 ) 5 ] 2 TiCl 2 crystallizes in the orthorhombic space group P 2 1 2 1 2 1 with cell dimensions a = 10.816(1), b = 8.132(1), c = 22.259(1) A; Z = 4. Full matrix, least-squares refinement converged to a final R index of 0.032 based on 1429 reflections. The configuration about the titanium atom is a distorted tetrahedron comprised of the two chlorine atoms and the centroids of the two η-cyclopentadienyl rings. Several ring methyl groups are bent considerably out of the cyclopentadienyl plane and away from the titanium atom. These out-of-plane deviations are attributable to chlorine—methyl crowding and methyl—methyl contacts between the two rings. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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