Comparative characterization of the coumarin composition ofSeseli campestre growing in Moldavia and in the Caucasus

Autor: V. N. Florya, D. Z. Abyshev, V. P. Zmeikov, I. P. Sidorova, Yu. B. Kerimov, A. Z. Abyshev
Rok vydání: 1982
Předmět:
Zdroj: Chemistry of Natural Compounds. 18:400-407
ISSN: 1573-8388
0009-3130
Popis: The results are given of the identification of (−)-trans-khellactone and its 4′-methyl ether and (−)-3′(S), 4′(S)-trans-3′-senecioyloxy-4′-angeloyloxy-3′,4′-dihydroseselin and of the establishment of the structure of three new khellactone derivatives — campestrol (VII), C19H22O6, [α]D20+ 32° (c 7.8; chloroform), campestrinol (X), C24H26O7, mp 116–118°C, and campestrinoside (I), C20H24O10, mp 172–173°C, [α]D −272.5° (c 4.7; ethanol). It has been shown on the basis of chemical and spectral characteristics that campesol, earlier described as a new substance, is a mixture of two isomeric compounds — 4′-hydroxy-3′-senecioyloxy-3′,4′-dihydroseselin and 3′-angeloyloxy-4′-hydroxy-3′,4′-dihydroseselin.
Databáze: OpenAIRE
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