5-Hydroxy-2 H -pyrrol-2-ones and not 2-aminofurans are the cycloaddition products between alkyl isocyanides and benzyliden-1,3-diketones
Autor: | Simona Dossena, Ugo Vendrame, Maurizio Mondoni, Sara Frattini, Enzo Cereda, Monica Quai |
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Rok vydání: | 2004 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 45:1413-1416 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2003.12.059 |
Popis: | New insights into the cycloaddition reaction between alkyl isocyanides and benzyliden-1,3-diketones are reported. 5-Hydroxy-N-substituted-2H-pyrrol-2-ones and not substituted furans, as previously reported, are formed. The proof of the structure relies on a thorough analytical investigation and X-ray crystallography. |
Databáze: | OpenAIRE |
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