Electronic States of Gaseous Fluorides of Scandium, Yttrium and Lanthanum

Autor:	M. W. Bastin, C. J. Pott, R. F. Barrow, D. L. G. Moore
Rok vydání:	1967
Předmět:	Multidisciplinary Materials science Inorganic chemistry chemistry.chemical_element Yttrium Scandium fluoride Spectral line chemistry.chemical_compound chemistry Lanthanum Physical chemistry Molecule Scandium Absorption (chemistry) Ground state
Zdroj:	Nature. 215:1072-1073
ISSN:	1476-4687 0028-0836
Popis:	SOME of the more obvious features in the spectra of scandium fluoride (ScF)1,2 and yttrium fluoride (YF)2,3 have been described. The absorption and fluorescence spectra of ScF in low temperature matrices have now been observed4, and calculations5 support the experimental finding that the ground state of ScF is 1Σ+. Some analogies6 may be drawn between the states of ScF and those of the isoelectronic molecule TiO. We have now carried out rotational analyses of a number of bands which have not been described before, and the purpose of this paper is to summarize the present position. For the most part the spectra have been observed in absorption in a carbon tube furnace at about 2,000° C, but some bands have also been photographed in thermal emission.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b607145d9613654d07925c2fd5d8ef5a https://doi.org/10.1038/2151072a0 Zobrazit plný text záznamu