Interaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate
Autor: | K. V. Balyan, H. B. Sargsyan, H. S. Nersisyan, Zh. A. Chobanyan, N. G. Hobosyan |
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Rok vydání: | 2016 |
Předmět: |
010405 organic chemistry
Acetylacetone Acetoacetic ester synthesis chemistry.chemical_element Regioselectivity General Chemistry Alkylation 010402 general chemistry Triple bond 01 natural sciences Medicinal chemistry 0104 chemical sciences Mercury (element) chemistry.chemical_compound chemistry Propargyl Organic chemistry Mercury(II) acetate |
Zdroj: | Russian Journal of General Chemistry. 86:1011-1016 |
ISSN: | 1608-3350 1070-3632 |
DOI: | 10.1134/s1070363216050042 |
Popis: | Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containing propargyl compounds by sodium salts of acetylacetone and acetoacetic ester with the formation of prototropic isomers has been shown. |
Databáze: | OpenAIRE |
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