Synergistic extraction of cobalt(II) with oxine/decanoic acid solution mixtures in benzene and chloroform

Autor: M. Aziz, Sh. G. Beheir, K. Shakir
Rok vydání: 1996
Předmět:
Zdroj: Journal of Radioanalytical and Nuclear Chemistry Articles. 207:117-127
ISSN: 1588-2780
0236-5731
DOI: 10.1007/bf02036531
Popis: Synergistic extraction of Co(II) with 8-hydroxyquinoline (Hq)/decanoic acid [(HR)2] solution mixtures in benzene and chloroform was carried out at 25°C. The aqueous ionic strength and the total concentration of cobalt(II) were 0.1 (NaCl) and 1·10−5–1·10−3M, respectively. The synergistic effect is interpreted by the formation of the mixed ligand ion-pair complexes: [(Coq(Hq)2(HR))+, R−] and [(Coq(Hq)2(HR)3)+, R−] in benzene and chloroform, respectively.
Databáze: OpenAIRE