Ruthenium(II) complexes with new tridentate ligands containing P, N, O donor atoms: highly efficient catalysts for transfer hydrogenation of ketones by propan-2-ol

Autor:	Hong Yang, Romain Mathieu, Noël Lugan, Marie Alvarez
Rok vydání:	1995
Předmět:	chemistry.chemical_compound Tridentate ligand chemistry Polymer chemistry Molecular Medicine Organic chemistry Noyori asymmetric hydrogenation chemistry.chemical_element Optically active Transfer hydrogenation Catalysis Acetophenone Ruthenium
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1721
ISSN:	0022-4936
DOI:	10.1039/c39950001721
Popis:	The complexes [RuCl2(PPh3)(L)] in which L is a tridentate ligand with P, N and O donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover ⩽ 118 800 h–1) in basic media; when L is optically active, no significant e.e. is observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b5e65a02fd951f3c69dd19fffd8323c9 https://doi.org/10.1039/c39950001721 Zobrazit plný text záznamu