Substrate inhibition: Oxidation of D-sorbitol and D-mannitol by potassium periodate in alkaline medium

Autor:	P. S. Radhakrishnamurti, Y. Lakshman Kumar, R. Venkata Nadh
Rok vydání:	2014
Předmět:	Arrhenius equation Inorganic chemistry Periodate Substrate (chemistry) Alkali metal Potassium periodate chemistry.chemical_compound symbols.namesake chemistry medicine symbols Hydroxide Sorbitol Mannitol Physical and Theoretical Chemistry medicine.drug
Zdroj:	Russian Journal of Physical Chemistry A. 88:774-778
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s003602441405015x
Popis:	In the oxidation of D-sorbitol and D-mannitol by potassium periodate in alkaline media, substrate inhibition was observed with both substrates, i.e., a decrease in the rate of the reaction was observed with an increase in the concentration of substrate. The substrate inhibition was attributed to the formation of stable complex between the substrate and periodate. The reactions were found to be first order in case of periodate and a positive fractional order with hydroxide ions. Arrhenius parameters were calculated for the oxidation of sorbitol and mannitol by potassium periodate in alkali media.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b5b828fffd8bbb137e02a2b12bfb7952 https://doi.org/10.1134/s003602441405015x Zobrazit plný text záznamu Full text from SpringerLink