Ultrathin type-II GaSb/GaAs quantum wells grown by OMVPE

Autor: Mike L. W. Thewalt, O.J. Pitts, C. X. Wang, J. A. H. Stotz, Simon P. Watkins, T.A. Meyer
Rok vydání: 2004
Předmět:
Zdroj: Journal of Crystal Growth. 269:187-194
ISSN: 0022-0248
DOI: 10.1016/j.jcrysgro.2004.05.013
Popis: Heterostructures containing monolayer (ML) and submonolayer GaSb insertions in GaAs were grown using organometallic vapour phase epitaxy. At the GaAs-on-GaSb interface, strong intermixing occurs due to the surface segregation of Sb. To form structures with relatively abrupt interfaces, a flashoff growth sequence, in which growth interruptions are employed to desorb Sb from the surface, was introduced. Reflectance-difference spectroscopy and high-resolution X-ray diffraction data demonstrate that interfacial grading is strongly reduced by this procedure. For layer structures grown with the flashoff sequence, a GaSb coverage up to 1 ML can be obtained in the two-dimensional (2D) growth mode. For uncapped GaSb layers, on the other hand, atomic force microscope images show that the 2D–3D growth mode transition occurs at a submonolayer coverage between 0.3 and 0.5 ML. Low-temperature photoluminescence spectra of multiple quantum well samples grown using the flashoff sequence show a strong quantum well-related peak which shifts to lower energies as the amount of Sb incorporated increases. The PL peak energies are consistent with a type-II band lineup at the GaAs/GaSb interface.
Databáze: OpenAIRE