Investigation of the mechanism of formation of chlorine atoms in chlorine-hydrogen plasmas

Autor:	D. V. Sitanov, V. I. Svettsov, Yu. V. Kirillov
Rok vydání:	2000
Předmět:	Hydrogen Chlorine atom Inorganic chemistry Electron concentration chemistry.chemical_element Electron Plasma Dissociation (chemistry) chemistry polycyclic compounds Chlorine Physics::Atomic Physics Physics::Chemical Physics Physical and Theoretical Chemistry Chain reaction
Zdroj:	High Energy Chemistry. 34:177-181
ISSN:	1608-3148 0018-1439
DOI:	10.1007/bf02762429
Popis:	To explain the trend of an experimental dependence for concentration of chlorine atoms in a discharge, the principal processes of the formation and decay in the plasma of a chlorine mixture with hydrogen were considered. The rate coefficients and rates of processes involving electrons were calculated by mathematical modeling in order to reveal the contribution of each process to the observed concentration of chlorine atoms. The greatest contribution is made by direct electron-impact dissociation. The experimental concentration of chlorine atoms at a high percentage of hydrogen is explained by an increase in electron concentration and, hence, in the rate of the direct dissociation process. It is suggested that chain reactions can make a substantial contribution to the formation of atoms at low hydrogen concentrations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b58cf1bb759f4cfde4e3a8c6bc73819a https://doi.org/10.1007/bf02762429 Zobrazit plný text záznamu Full text from SpringerLink