Structural and electronic properties of (2,2-trans)-dirhodium(II) tetrakis(N-phenylacetamidate)

Autor:	Grant N. Holder, Cassandra T. Eagle, Rosa D. Bailey, David G. Farrar, William T. Pennington
Rok vydání:	2000
Předmět:	Stereochemistry Organic Chemistry Solid-state Aromaticity Biochemistry Medicinal chemistry Adduct Inorganic Chemistry Benzonitrile chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry Pi backbonding Electronic properties
Zdroj:	Journal of Organometallic Chemistry. 596:90-94
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(99)00556-2
Popis:	We have synthesized and characterized the first known 2,2-trans isomer of the N-substituted dirhodium(II) tetrakisacetamidate, Rh2(RNAc)4, class of compounds. The bis benzonitrile adduct exhibits a unique orthogonal arrangement of the axial aromatic rings in the solid state. Structural and electronic features suggest the presence of π-backbonding.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b5753abd54bb4f030d5d0aa529741b06 https://doi.org/10.1016/s0022-328x(99)00556-2 Zobrazit plný text záznamu Full Text from ScienceDirect