Magnetic Properties of the Dinuclear Copper(II) Compounds Bridged by Oxalato-Type Ligands
| Autor: | Shuji Emori, Kyoko Todoko |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
medicine.drug_class Stereochemistry Ligand Infrared spectroscopy chemistry.chemical_element Carboxamide General Chemistry Resonance (chemistry) Copper Magnetic susceptibility chemistry.chemical_compound Crystallography Dicarboxylic acid chemistry medicine Carboxylate |
| Zdroj: | Bulletin of the Chemical Society of Japan. 66:3513-3515 |
| ISSN: | 1348-0634 0009-2673 |
| DOI: | 10.1246/bcsj.66.3513 |
| Popis: | Various dinuclear copper(II) compounds bridged by the oxalato, oxamato, and oxamidato ligands were prepared and characterized by means of magnetic susceptibility and IR spectroscopy. The strong antiferromagnetic couplings through their carboxylate or carboxamidate groups are interpreted in terms of the ligand basicities and the electron withdrawal due to the resonance of the substituents. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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