Essential oil of Plectranthus tenuicaulis for flavour and fragrance: Synthesis of derivatives from natural and synthetic 6,7-epoxyocimenes
| Autor: | Raphaël Bikanga, Chantal Menut, Hervé Casabianca, Jean Jacques Anguile, Thomas Makani, Abdelhamid Agrebi, Huguette Agnaniet, Jacques Lebibi, Alain Morère |
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| Rok vydání: | 2012 |
| Předmět: |
biology
010405 organic chemistry Plectranthus Flavour chemistry.chemical_element General Chemistry 010402 general chemistry Mass spectrometry biology.organism_classification 01 natural sciences Sulfur 0104 chemical sciences law.invention chemistry law Organic chemistry Gas chromatography Two-dimensional nuclear magnetic resonance spectroscopy Electron ionization Essential oil Food Science |
| Zdroj: | Flavour and Fragrance Journal. 27:188-195 |
| ISSN: | 0882-5734 |
| DOI: | 10.1002/ffj.3087 |
| Popis: | (R)-(E)-6,7-Epoxyocimene, the major constituent of the essential oil from Plectranthus tenuicaulis, as well as the racemic (Z)-isomer previously synthesized from commercial (Z)-beta-ocimene were used as starting material for the synthesis of fragrant derivatives. Among the 14 compounds obtained from these precursors (alcohols, diols, diepoxy, sulfur and carbonyl derivatives), four were described for the first time and three were enantiomerically pure. All compounds were fully characterized by one- and two-dimensional nuclear magnetic resonance analysis as well as by gas chromatography and mass spectroscopy (electron ionization). Additionally, their odour properties were evaluated |
| Databáze: | OpenAIRE |
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