Synthesis and photochromic properties of new nonsymmetric dihetarylethenes — indole and thiophene derivatives

Autor: V. P. Rybalkin, Evgenii N. Shepelenko, Nadezhda I. Makarova, Vladimir I. Minkin, Anatoly V. Metelitsa, Vladimir A. Bren, V. S. Kozyrev, P. V. Levchenko
Rok vydání: 2011
Předmět:
Zdroj: Russian Chemical Bulletin. 60:1899-1905
ISSN: 1573-9171
1066-5285
DOI: 10.1007/s11172-011-0286-5
Popis: New nonsymmetric dihetarylethenes were synthesized: 3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)furan-2,5-dione and photochromic 1-alkyl-(1-aryl)-3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-(3-thienyl)-1(H)-pyrrole-2,5-diones. The absence of benzoannulation in the indole moiety results in the enhancement of the efficiencies of fluorescence and photocyclization of noncyclic isomers compared to the benzoindole derivatives.
Databáze: OpenAIRE