Photoelectron studies of metal carbonyls. Part 2.—The valence region photoelectron spectra of the group VIA hexacarbonyls

Autor:	David M. Gibson, Peter Burroughs, A.F. Orchard, D. Robert Lloyd, Brian R. Higginson
Rok vydání:	1973
Předmět:	Crystallography Valence (chemistry) Physics::Instrumentation and Detectors Chemistry Physics::Atomic and Molecular Clusters Metal carbonyl Molecular orbital Atomic physics Multiplet Spectral line Ultraviolet photoelectron spectroscopy
Zdroj:	J. Chem. Soc., Faraday Trans. 2. 69:1659-1668
ISSN:	0300-9238
DOI:	10.1039/f29736901659
Popis:	He(I), He(II) and valence region X-ray photoelectron spectra are reported for the Group VIA hexacarbonyls and are assigned on the basis of published molecular orbital calculations. A pronounced increase in intensity of the first photoelectron band is observed on descending the group, and multiplet structure is clearly discernible on this band in the case of W(CO)6.
Databáze:	OpenAIRE
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