Synthesis of New Methano[1,5]dioxocines via a Domino Reaction of 4-Hydroxy-2H-pyran-2-ones / 4-Hydroxy-2H-chromen-2-ones with Acyclic 1,3-Diketones

Autor:	Uwe Beifuß, Heiko Leutbecher, Jürgen Conrad
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Molecular recognition chemistry Cascade reaction Pyran Stereochemistry Enantioselective synthesis Molecule General Chemistry Chirality (chemistry) Tröger's base
Zdroj:	Zeitschrift für Naturforschung B. 63:871-876
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2008-0711
Popis:	Since the discovery of Troger’s base numerous structural analogs with a central [1,5]diazocine skeleton were synthesized [3, 4]. Both the chirality and the rigid concave structure of the methano[1,5]diazocine skeleton are the reasons why Troger’s base und derivatives thereof have found interest in the design of receptors for the molecular recognition of neutral molecules [5], as chiral solvating agents [6], and in the field of asymmetric synthesis [7].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b5456e741556e9280e908352a75bd17d https://doi.org/10.1515/znb-2008-0711 Zobrazit plný text záznamu