1,2-Diethoxyethane catalyzed oxidative cleavage of gem-disubstituted aromatic alkenes to ketones under minimal solvent conditions
| Autor: | Ying-Wu Lin, Wei-Min He, Tang-Yu Zeng, Xin-Jie Chen, Ji-Hui Deng, Kai-Jian Liu, Ying Huang, Zhong Cao |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
inorganic chemicals
Chemistry Potential risk 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chemical synthesis Combinatorial chemistry 0104 chemical sciences Ambient air Catalysis Solvent 0210 nano-technology Oxidative cleavage |
| Zdroj: | Chinese Chemical Letters. 31:1868-1872 |
| ISSN: | 1001-8417 |
| Popis: | Aerobic oxidation using pure dioxygen gas as the oxidant has attracted much attention, but its application in synthetic chemistry has been significantly hampered by the complexity of catalytic system and potential risk of high-energy dioxygen gas. By employing 1,2-diethoxyethane as a catalyst and ambient air as an oxidant, an efficient protocol for the construction of various aryl-alkyl and diaryl ketones through oxidative cleavage of gem-disubstituted aromatic alkenes under minimal solvent conditions has been achieved. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect