OBSERVATION OF A RATE ENHANCING ANION-IONIC STRENGTH INTERACTION IN THE POLAROGRAPHIC REDUCTION OF Ga(III) IN HALIDE-Sr(C104)2MEDIA
Autor: | E. D. Moorhead, C. A. Stoll, G. M. Frame |
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Rok vydání: | 1968 |
Předmět: | |
Zdroj: | Analytical Letters. 1:861-869 |
ISSN: | 1532-236X 0003-2719 |
DOI: | 10.1080/00032716808051716 |
Popis: | Preliminary polarographic experiments have revealed that in sufficiently concentrated alkaline earth perchlorates C1−, Br−, and I− catalyze the reversible reduction of Ga(III) to the metal. The results are discussed relative to earlier work which indicated that reversibility is realizable only in the presence of SCN− or N3 − |
Databáze: | OpenAIRE |
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