OBSERVATION OF A RATE ENHANCING ANION-IONIC STRENGTH INTERACTION IN THE POLAROGRAPHIC REDUCTION OF Ga(III) IN HALIDE-Sr(C104)2MEDIA

Autor: E. D. Moorhead, C. A. Stoll, G. M. Frame
Rok vydání: 1968
Předmět:
Zdroj: Analytical Letters. 1:861-869
ISSN: 1532-236X
0003-2719
DOI: 10.1080/00032716808051716
Popis: Preliminary polarographic experiments have revealed that in sufficiently concentrated alkaline earth perchlorates C1−, Br−, and I− catalyze the reversible reduction of Ga(III) to the metal. The results are discussed relative to earlier work which indicated that reversibility is realizable only in the presence of SCN− or N3 −
Databáze: OpenAIRE