Computer Simulation of a Simple Model for Rotational Moment Fluctuations in an Associating Liquid

Autor:	M. Stockhausen, H.-G. Köhne
Rok vydání:	1995
Předmět:	Experimental physics Moment (mathematics) Physics Simple (abstract algebra) General Physics and Astronomy Rotational temperature Statistical physics Physical and Theoretical Chemistry Rotational partition function Mathematical Physics
Zdroj:	Zeitschrift für Naturforschung A. 50:352-356
ISSN:	1865-7109 0932-0784
DOI:	10.1515/zna-1995-4-506
Popis:	With regard to the interpretation of dielectric relaxation spectra of associating liquids such as alcohols, a two state model for the rotational tumbling motion of a dipole is considered: The moment (of constant magnitude) is assumed to undergo stochastic tumbling during a "free" state, alternating with an "associated" state where for a certain residence time the rotational motion can be neglected. One particle autocorrelation functions according to that model are calculated numerically. In any case, they can well be described as sum of (at most) two exponentials. The corresponding parameters are given as function of "association" probability and residence time
Databáze:	OpenAIRE
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