Dynamics across a Free Surface Reflect Interplay between Density and Cooperative Length: Application to Polystyrene

Autor: Jane E. G. Lipson, Ronald P. White
Rok vydání: 2021
Předmět:
Zdroj: Macromolecules. 54:4136-4144
ISSN: 1520-5835
0024-9297
DOI: 10.1021/acs.macromol.0c02742
Popis: It is now generally agreed that the most dramatic influence of a free surface on local relaxation dynamics occurs over the first 10 nm from the surface. Using the cooperative free volume (CFV) rate...
Databáze: OpenAIRE