Thermal energy rate constants for the reactions NO−2 + Cl2 → Cl−2 + NO2, Cl−2 + NO2 → Cl− + NO2Cl, SH− + NO2 → NO−2 + SH, SH− + Cl2 → Cl−2 + SH, and S− + NO2 → NO−2 + S

Autor:	Eldon E. Ferguson, F.C. Fehsenfeld, D.B Dunkin
Rok vydání:	1972
Předmět:	Reaction rate constant business.industry Computational chemistry Chemistry General Physics and Astronomy Physical chemistry Physical and Theoretical Chemistry business Thermal energy Ion
Zdroj:	Chemical Physics Letters. 15:257-259
ISSN:	0009-2614
DOI:	10.1016/0009-2614(72)80162-3
Popis:	It is found that charge-transfer on NO − 2 with Cl 2 is fast at thermal energy. The Cl − 2 ion reacts with NO 2 to produce Cl − and NO 2 Cl, and SH − charge-transfers rapidly with both Cl 2 and NO 2 . From the exothermicities implied it is deduced that EA (SH) 2 ) 2 ) or EA (NO 2 ) = 2.38 ± 0.06 eV and EA (Cl 2 = 2.46 ± 0.14 eV.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b5116bf75b7abf65818fcc1413ab9939 https://doi.org/10.1016/0009-2614(72)80162-3 Zobrazit plný text záznamu