Synthesis and determination of the electron transfer numbers of alkynyl bridged multiferrocenyl derivatives
Autor: | Li-Min Han, Yan-Qiang Ma, Quan-Ling Suo, Ning Zhu, Mei-Hua Luo |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Inorganic Chemistry Communications. 11:873-875 |
ISSN: | 1387-7003 |
DOI: | 10.1016/j.inoche.2008.04.017 |
Popis: | Multiferrocenyl derivatives FcC(CH3)2Fc′–C C–Fc(A) (Fc = C5H5FeC5H4, Fc′ = C5H5FeC5H3) and FcC(CH3)2Fc′–C C–C C–Fc′C(CH3)2Fc (B) have been synthesized and characterized by MS, NMR, FT-IR and elemental analysis. The molecular structure of compound A was given by single crystal X-ray diffraction. The electron transfer numbers of two compounds were determined by cyclic voltammetry and chronoamperomeric technique. |
Databáze: | OpenAIRE |
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