A deprotonation pathway to reactive [B]CH2 boraalkenes

Autor:	Karel Škoch, Chaohuang Chen, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker
Rok vydání:	2022
Předmět:	Inorganic Chemistry
Zdroj:	Dalton Transactions. 51:7695-7704
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d2dt01193j
Popis:	The BH compounds IMes(ArF)BH(NTf2) (ArF: C6F5 or FpXyl) were converted to the IMes(ArF)BCH2 boraalkenes in a three step reaction sequence of B-methylation with methyllithium, hydride abstraction and deprotonation.
Databáze:	OpenAIRE
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