Sulfamides and Glymes as Aprotic Solvents for Lithium Batteries
| Autor: | Yves Choquette, Michel Armand, Gessie Brisard, Gérald Perron, Denis Gravel, Nacer Slougui, Dany Brouillette, Michel Parent, Jacques E. Desnoyers |
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| Rok vydání: | 1998 |
| Předmět: |
Conductive polymer
Renewable Energy Sustainability and the Environment Inorganic chemistry chemistry.chemical_element Condensed Matter Physics Oligomer Surfaces Coatings and Films Electronic Optical and Magnetic Materials Solvent chemistry.chemical_compound chemistry Electrical resistivity and conductivity Materials Chemistry Electrochemistry Physical chemistry Reactivity (chemistry) Lithium Imide Phase diagram |
| Zdroj: | Journal of The Electrochemical Society. 145:3500-3507 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.1838834 |
| Popis: | In view of the high reactivity of the lithium metal, lithium batteries must operate in an aprotic environment, which can either be a conducting polymer, a liquid solvent, or a mixture of them. Two families of aprotic liquids were considered as solvents for lithium bis(trifluoromethylsulfone)imide (LiCF{sub 3}SO{sub 2}NSO{sub 2}CF{sub 3} or LiTFSI). The first one is the substituted sulfamides, R{sub 1}R{sub 2}NSO{sub 2}NR{sub 3}R{sub 4}, where the R groups are either methyl, ethyl, or methoxyethyl (CH{sub 2}CH{sub 2}OCH{sub 3}), and the second one is the glymes, CH{sub 3}O(CH{sub 2}CH{sub 2}O){sub n}CH{sub 3}, for n up to 10. The phase diagrams, potential windows, conductivities, and the lithium interfacial resistances of the solutions were investigated, often as a function of temperature. The potential use of these solvents for different types of batteries is discussed. |
| Databáze: | OpenAIRE |
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