Crystal Structure of Piezoelectric Ferromagnetic Gallium Iron Oxide

Autor:	S. C. Abrahams, J. L. Bernstein, J. M. Reddy
Rok vydání:	1965
Předmět:	Iron oxide General Physics and Astronomy chemistry.chemical_element Crystal structure chemistry.chemical_compound Crystallography Lattice constant Octahedron chemistry Atom Tetrahedron Orthorhombic crystal system Physical and Theoretical Chemistry Gallium
Zdroj:	The Journal of Chemical Physics. 42:3957-3968
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1695868
Popis:	The crystal structure of Ga2—xFexO3, with 0.7≤x≤1.4, has been determined at 298°K by x‐ray diffraction. Ga2—xFexO3 crystallizes in the orthorhombic system, space group Pc21n, with lattice constants a = 8.7512±0.0008, b = 9.3993±0.0003, c = 5.0806±0.0002 A and eight formula weights in the unit cell. The complete scattering pattern was measured with PEXRAD to (sinθ)/λ≤1.02 A−1. One gallium atom in the asymmetric unit is in a tetrahedral site, the other gallium and the two iron atoms are in octahedral sites. For x>1, the excess iron partly occupies the octahedral gallium site: the iron sites are to a smaller extent occupied by gallium. The gallium tetrahedron is very nearly regular, with Gatetr−0 = 1.846±0.005 A. The gallium octahedron is irregular, with average Gaoct−0 = 2.026±0.004 A; the iron octahedra are somewhat more irregular, with average Feoct−0 = 2.036±0.004 and 2.049±0.004 A in the two crystallographically independent octahedra. The oxygen atoms pack in pseudohexagonal layers with a double‐hexagon...
Databáze:	OpenAIRE
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