Modification of photonic properties in porphyrin-infiltrated opal crystals
Autor: | L. Rasteniene, A. Suchodolskis, J. Sabataityte, A. Reza, I. Simkiene, G.J. Babonas, D. Kurdyukov, M. Baran, R. Szymczak, R. Vaisnoras, V. Golubev |
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Rok vydání: | 2007 |
Předmět: |
Materials science
Aqueous solution business.industry Nanophotonics Analytical chemistry Stopband Condensed Matter Physics Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Magnetic field Optics Hardware and Architecture Basic solution Electrical and Electronic Engineering Photonics business Absorption (electromagnetic radiation) Photonic crystal |
Zdroj: | Photonics and Nanostructures - Fundamentals and Applications. 5:125-128 |
ISSN: | 1569-4410 |
DOI: | 10.1016/j.photonics.2007.07.006 |
Popis: | Structural, optical and magnetic properties of porphyrin-infiltrated opal hybrid structures were investigated. Bulk samples of synthetic opal were grown by sedimentation technique from colloidal solution of SiO2 spheres of diameter � 250 nm. The structure of the samples was examined by atomic force microscopy. The photonic properties of crystals were investigated by optical measurements in transmission and reflection modes. The stop band was observed in the region 510‐550 nm. The photonic properties of synthetic opal crystals were modified by infiltration with aqueous basic solution of iron‐porphyrin (FeTPPS) of concentration � 1.0 mM. In hybrid samples the absorption bands typical of FeTPPS were observed in the vicinity of the opal stop band. Magnetic properties of FeTPPS-infiltrated opal samples have been studied at 5‐300 K in magnetic fields up to 5 T. The FeTPPS-infiltrated opal crystals can be considered as the structures perspective for magnetophotonic devices. # 2007 Elsevier B.V. All rights reserved. |
Databáze: | OpenAIRE |
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