Cluster model of the step-shaped adsorption isotherm in metal–organic frameworks
| Autor: | E. V. Butyrskaya, S. A. Zapryagaev |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Sorbent
Materials science Thermodynamics 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Pressure range chemistry.chemical_compound Monomer Adsorption chemistry Mechanics of Materials Cluster (physics) Molecule General Materials Science Metal-organic framework Sorption isotherm 0210 nano-technology |
| Zdroj: | Microporous and Mesoporous Materials. 322:111146 |
| ISSN: | 1387-1811 |
| DOI: | 10.1016/j.micromeso.2021.111146 |
| Popis: | The CO2 adsorption phenomenon in IRMOF-1 is considered on the basis of the cluster adsorption model. It has been shown that sorbate molecules are sorbed on the sorbent surface in the form of monomers and clusters of various dimensions. An explanation is proposed for the stepwise increase in the sorbate loading by the rapid sorbate adsorption as the n CO2 clusters within a narrow pressure range. For the studied system, equations are obtained that describe the experimental isotherms for temperatures 195, 208, 218, and 298K. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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