ChemInform Abstract: YNAZIRIDINES AND THEIR REACTIONS WITH AMINES

Autor:	D. A. Tikhomirov, Yu. V. Shubina, A. V. Eremeev
Rok vydání:	1985
Předmět:	chemistry.chemical_compound Reflection (mathematics) Ultraviolet visible spectroscopy Nitrogen atom chemistry Electrophile General Medicine Triple bond Photochemistry Carbonyl group
Zdroj:	Chemischer Informationsdienst. 16
ISSN:	0009-2975
Popis:	On the basis of the results of IR and UV spectroscopy, a considerable decrease in the efficacy of the conjugation of the unshared pair of the nitrogen atom with a carbonyl group in ynaziridines as compared with ynamines has been shown. The difference in the electronic structures of these compounds finds its reflection in their chemical behavior: the electrophilicity of the triple bond in an ynaziridine is higher than that in the analogous ynamine in reactions with amines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b49303537ca552466b9d9686219bd287 https://doi.org/10.1002/chin.198539182 Zobrazit plný text záznamu Plný text