Synthesis, characterization, and reactivity of new clusters that contain the [MFe3S4]0 core, M = molybdenum, tungsten. A weakly perturbed [MFe3S4]0 unit structurally and electronically analogous to the reduced three-ion centers in ferredoxins

Autor:	A. Simopoulos, A. Kostikas, V. Papaefthymiou, Saleem A. Al-Ahmad, D. Coucouvanis, Athanasios Salifoglou
Rok vydání:	1992
Předmět:	Stereochemistry chemistry.chemical_element Trimer General Chemistry Biochemistry Catalysis chemistry.chemical_compound Crystallography Colloid and Surface Chemistry chemistry Cubane Molybdenum Yield (chemistry) Molecule Reactivity (chemistry) Acetonitrile Ferredoxin
Zdroj:	Journal of the American Chemical Society. 114:2472-2482
ISSN:	1520-5126 0002-7863
Popis:	The synthesis, characterization, and reactions of the new «cubane»-type clusters (ET 4 N) 3 [Fe 3 S 4 L 3 M(CO) 3 ], M=MO, L=EtS - , BzS - , p-OMePhS - , PhO - , Cl - ; M=W, L=p-OMePhS - , are described in detail. These clusters are obtained in a good yield as (ET 4 N) + salts, by the reaction of the [Fe 3 S 4 L 4 ] 3- linear trimer with M(CO) 3 (MeCn) 3 , M=Mo, W
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b489c85202b8ec6db78ceef39e1e689b https://doi.org/10.1021/ja00033a023 Zobrazit plný text záznamu