A new property of geminal bishydroperoxides: Hydrolysis with the removal of hydroperoxide groups to form a ketone

Autor:	Igor B. Krylov, G. I. Nikishin, O. B. Krivykh, Alexander O. Terent'ev, Yu. N. Ogibin
Rok vydání:	2010
Předmět:	Steric effects chemistry.chemical_classification chemistry.chemical_compound Hydrolysis Organic peroxide Ketone Geminal chemistry General chemistry Organic chemistry General Chemistry Hydrogen peroxide
Zdroj:	Russian Journal of General Chemistry. 80:1667-1671
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363210080165
Popis:	A new property of geminal bishydroperoxide was discovered: the ability to hydrolyze in acid medium in the presence of hydrogen peroxide with the formation of ketones. The most resistant to hydrolysis are the cyclic C6-bishydroperoxydes: at room temperature within one day they are practically not hydrolyzed; less stable is bishydroperoxycycloheptane (C7): in a day its one fifth part is hydrolyzed. Bishydroperoxydes with the cycles of C8 and C12 for the same time hydrolyzed to 80 and 90% respectively. Of the two linear bishydroperoxydes, 2,2-dihydroperoxydecane, with sterically unhindered center, is more resistant to hydrolysis than 6,6-dihydroperoxyundecane.
Databáze:	OpenAIRE
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